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Cleaning Black Spot on Lip of Saucepan Lid?

My husband used to be the cook and dishwasher in this house. I just recently took over. I'm trying to get our pots and pans back to new looking. I just saw some black on the lid of the saucepan. I tried to scrub it, but I don't have any scour pads right now. It wouldn' come off. I had just soaked the pan in baking soda, vinegar, and water. I hope the black is not mold from food residue, is it? And how to I get rid of it. I will purchase some scour pads.

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By T L

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