How do I clean/whiten old pillowcases that are stained yellow and have a few rust spots without bleaching out the embroidery on the case?
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As a general rule sunshine and water will remove most storage yellow stains but may not remove any other type stain completely. I would start with just wetting the case and lay it in the sunshine and keep wetting it for a day. See how this does before attempting any other solution as your case may also be weakened and any other solutions may damage the material. Be sure to use a lingerie bag when washing to keep them from a lot of motion/twisting.
Try washing in borax and drying in the sun.
We use baking soda with our detergent and air dry in the sun. Good luck!
Wash, soak in lemon juice, and put put in the sun to dry
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