For removing tar and grease from clothing, I first use some WD-40 and work it into the spot until it starts to break down. Then I use some cream-type hand cleaner (available at an auto-parts store) and rub that into the remaining spot. Then, if needed, I use a small bit of baby shampoo and warm water to remove anything that is left before tossing in the clothes washer. This has always worked with even the hardest roofing tars and auto grease stains. Good Luck!
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